Download Spectroscopic Properties of Inorganic and Organometallic by G Davidson, Keith B Dillon PDF

By G Davidson, Keith B Dillon

Content material: bankruptcy 1: NMR spectroscopy within the liquid and gasoline levels; bankruptcy 2: stable nation NMR spectroscopy; bankruptcy 3:Nuclear quadrupole resonance spectroscopy; bankruptcy four: attribute vibrations of compounds of major workforce parts; bankruptcy five: Vibrational spectra of transition point compounds; bankruptcy 6: Vibrational spectra of a few co-ordinated ligands; bankruptcy 7: Gas-phase molecular constructions made up our minds by means of electron diffraction

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Extra info for Spectroscopic Properties of Inorganic and Organometallic Compounds, Volume 39

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IPr (1H, 13C, 31P);649 Ni(L)(RS3), where L = NHPnPr3, NHPCy3, NHSPh2, PnPr3, RS32À = bis(2-mercapto-3-trimethylsilylphenyl)sulfide(2-) (1H, 31P);650 Pd(H)(X)(L)2, where X = Cl, SnCl3. L = PPh3, PCy3 (1H, 31P, 119Sn, 1H-119Sn HMQC);651 Pd(COCH2CH3)(TsO)(PPh3)2 (1H, 31P);652 (210), where R = Me, Et, i Pr, Ph (1H, 13C);653 [{(Z3-C3H5)Pd[C(N{R}CH)2]}2(m-X)]+, where X = Cl, I, R = t Bu, C6H3-2,6-iPr2 (1H, 13C);654 (211a), where Ar = (211b) (1H, 13C, 1H–13C HSQC);655 (212) and related species (1H, 13C{1H}, 31P{1H});656 (213), where PR3 = PCyMePh (1H, 2-D);657 [{CH2(MeCNAr)2}Pd(Z3-C4H7)]+, where Ar = Ph, 2MeC6H4, 2,6-iPr2C6H3 (1H, 13C{1H});658 [Pd12(m3-I)2(m4-I)3(m2-CO)6(PEt3)6]+ (1H, 13 C, 31P);659 (214) (1H, 13C, 31P);660 trans-[PdCl2{NaQC(R)ONQCb(C6H2R 0 3)Na,Cb}2]2, where R = Me, Et, CH2CN, NMe2, Ph; R 0 = Me, OMe (1H, 13 C{1H});661 (215) and related complexes (1H, 31P, 1-D and 2-D);662 MCl2(L), M = Pd, Pt; L = 1-R-3,5-bis(2-pyridyl)pyrazole, R = ethyl, octyl (1H, 13C{1H});663 44 | Spectrosc.

G. 468 19F–1H HMQC NMR spectra of (140) reveal close contact between methyl groups on the phosphine and acyl ligands at Spectrosc. Prop. Inorg. Organomet. 479 36 | Spectrosc. Prop. Inorg. Organomet. 487 1H–1H COSY and 31P{1H} NMR spectra were used to show Spectrosc. Prop. Inorg. Organomet. 489 Other NMR studies were reported for: PhCCo2M(CO)n[(Z)– Ph2PCHQCHPPh2]Cp (M = Mo, n = 6; M = Ni, n = 4) (1H, 31P);490 (147) and related complexes (1H, 13C, 31P);491 (148) (R = CH2NH2, C6H4NH2, C(O)NH2, C(Cy)HNH2 (1H, 31P);492 (149) (31P);493 (150) (1H, 13C);494 CpCo(CO)[P(Ar)2(Ar 0 )], where Ar = 4-Me3SiC6H4, Ph; Ar 0 = 4-Me3SiC6H4 (13C, 31P);495 (151), where Ar = 2,6-iPr2C6H3, 2,4,6-iPr3C6H2 (1H, 2H, 13C, 19F);496 Co(II) (and other metal) complexes of (152) (1H, 13C);497 [Co(dienbpc)Cl]ZnCl4, where dienbpc = [2-(2-aminomethylamino)ethyl-amine]-di-pyridin-2-yl-methanol (1H, 13C);498 Co(tacn)23+, [(tacn)Co(m-NH2)Co(tacn)]3+, where tacn = 1,4,7-triazacyclononane (1H, 13 C{1H});499 CoL3+, where L = (153) (1H, 13C, 59Co);500 a-cis-[Co(trien)(L)]3+, where trien = triethylenetetramine, L = bipy, phen (1-D, 2-D NMR);501 [(TIMENxyl)Co(X)]+, where X = Cl, O2, CO, TIMENxyl = tris[2-(3-xylylimidazol-2ylidene)ethyl]amine (1H);502 asym-[Co(L-O)Cl](ClO4)2, where L = (154) (1H, 13 C);503 [Co2(L)Cl2]4+ (L = (155)) (1H, 13C);504 Co(II), Ni(II), Cu(II), Zn(II) complexes of Schiff bases from acetylferrocene and 2-aminophenol, 2-amino-5-picoline, 2-amino-5-chlorophenol (1H, 13C);505 binuclear complexes [M2+(L)M2+(ClÀ)2], where M = Co, Ni, H2L = N,N-bis(salicylidene)-1,10-phenanthroline-5,6-diamine (1H, 13C);506 ML2Cl2, M(L)Cl, where M = Co, Ni, Cu, Zn, L = a b-lactam 38 | Spectrosc.

G. 743 1H-15N HSQC NMR spectra were used to determine the coordination of copper(I) in apo-CusF—a protein involved in copper and silver resistance in E. g. 757 48 | Spectrosc. Prop. Inorg. Organomet. ) (1H, 13C, 31P);772 Cu(I)(dppmS2, where dppmS2 = 1,1bis(diphenylthiophosphinyl)methane;773 phospha-1,1-diselenolato complexes of Cu, Ag, Zn or Cd (1H,31P, 77Se);774 [Cu(TeCF3)2]À (19F);775 Cu3Cl3{mPt(R)C(NMe2)2}3, where R = Ph, tBu (1H, 13C{1H}, 31P{1H});776 (247), where X = Br, I, ClO4 etc. (1H, 13C, 31P);777 [AgX:dppf]n adducts, where dppf = Spectrosc.

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